Intramolecular charge transfer complexes. 26. Copolymers of (9-anthryl)methyl- and 1-(9-anthryl)ethylmethacrylate with methacryloyl-β-hydroxyethyl-3,5-dinitrobenzoate

✍ Scribed by C. I. Simionescu; M. Grigoraş; V. Bǎrboiu

• Publisher: John Wiley and Sons
• Year: 1985
• Tongue: English
• Weight: 317 KB
• Volume: 36
• Category: Article
• ISSN: 0323-7648
• DOI: 10.1002/actp.1985.010360202

✦ Synopsis

Dedicated to Professor Dr. habil. Burkart Philipp on occasion of his 60th birthday

Radical copolymerization of (9-anthry1)methyl-and 1-(9-anthryl)ethyl-methacrylate with methacryloyl-p-hydroxyethyl-3,5-dinitrobenzoate proceeds through a mechanism which involves intermonomeric complex participation leading to intramolecular charge transfer complexes. The substitution on the a position of the donor group decreases the degree of intramolecular complexation.

Intramolekzdare Charge-Transfer-Komplexe. 26. Copolymer uon (g-Anthryl)-methyl-und 1-(9-Anthryl)-ethyl-methacrylat mit Methacryloyl-~-hydroxyethyl-3,5-dinitro~enzout

Die radikalische Copolymerisation von (9-Anthry1)-methyl-und 1-(9-Anthryl)-ethyl-methacrylat mit Methacryloylp-hydroxyethyl-3,5-dinitrobenzoat erfolgt nach einem Mechanismus, an dem ein Intermonomerkomplex beteiligt ist, und ergibt intramolekulare Charge-Transfer-Komplexe. Substitution in der a-Stellung der Donorgruppe verringert den Grad der intramolekularen Komplexbildung.

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