Intramolecular Chain Transfer to Polymer in the Emulsion Polymerization of 2-Ethylhexyl Acrylate
β Scribed by Plessis, Christophe; Arzamendi, Gurutze; Alberdi, Juan M.; Agnely, Mathias; Leiza, Jose R.; Asua, Jose M.
- Book ID
- 125899868
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 79 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Propagation rate coefficients (__k__~p~) for 2βhydroxyethyl acrylate (HEA) have been determined by pulsedβlaser polymerization (PLP) combined with sizeβexclusion chromatography (SEC) between 20 and 60βΒ°C using pulse repetition rates of 50 and 100βHz. The success of PLPβSEC under these c
## Abstract Unusual difficulties are faced in the determination of propagation rate coefficients (__k__~p~) of alkyl acrylates by pulsedβlaser polymerization (PLP). When the backbiting is the predominant chain transfer event, the apparent __k__~p~ of acrylates determined in PLP experiments for diff