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Intramolecular CH Activation in Complexes with MoBi Metal Bonds

✍ Scribed by Stefan Roggan; Christian Limberg; Burkhard Ziemer; Marcus Brandt

Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
162 KB
Volume
43
Category
Article
ISSN
0044-8249

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“Bent Bonds” between Bismuth and Carbon
“Bent Bonds” between Bismuth and Carbon Atoms as a Result of CH Activation in MoBi Complexes
✍ Stefan Roggan; Gregor Schnakenburg; Christian Limberg; Steffen Sandhöfner; Hans 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 464 KB

## Abstract The reaction of molybdocenedihydride with two equivalents of [Bi(O__t__Bu)~3~] proceeds via alcohol elimination and provides the compound [Cp~2~Mo{Bi(O__t__Bu)~2~}~2~] (1), which contains two MoBi metal bonds, in good yields. If the two reagents are employed in a 1:1 ratio continuative