Intramolecular catalysis. Part 2. Mechanism of hydrolysis of alkyl 8-hydroxy-1-naphthoates
β Scribed by Bowden, Keith; Law, David; Ranson, Richard J.
- Book ID
- 121335092
- Publisher
- Royal Society of Chemistry
- Year
- 1977
- Tongue
- English
- Weight
- 769 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1472-779X
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π SIMILAR VOLUMES
IT is well-established that the hydrolysis of alicyclic axial acetates ie accelerated by the presence of an axial hydroxyl group at the 3-position. Earlier work in these laboratories has demonstrated the facilitation In strophanthidin 3-acetate 1,2 and in derivative8 of cevine, 1,2 gennine, 3 and pr
The rates of hydrolysis of N-(2&4-hydroxybenzylidene)-2-aminobenzothiazoles has been studied in the pH range 4-13 in a 10% dioxane-water system and in various nonionic surfactant systems. The reaction is found to be due to water mediated intramolecular general base catalysis within the pH range 4.0