Intramolecular Carbostannylation of Alkynes Catalyzed by Silver(I) Species
✍ Scribed by Susana Porcel; Antonio M. Echavarren
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 177 KB
- Volume
- 119
- Category
- Article
- ISSN
- 0044-8249
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✦ Synopsis
Cyclizations of a,w-enynes catalyzed by transition-or maingroup metals provide highly functionalized carbo-and heterocycles under mild conditions in atom-economical processes. [1] We have previously shown that reactions of allylsilanes or allylstannanes 1 with different metal catalysts proceed to form hetero-or carbocycles 2 (Scheme 1). [2,3]
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