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Intramolecular anodic olefin coupling reactions: the use of allyl- and vinylsilanes in the construction of quaternary carbons

โœ Scribed by Moeller, Kevin D.; Hudson, Christine M.; Tinao-Wooldridge, Luzviminda V.

Book ID
126018914
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
276 KB
Volume
58
Category
Article
ISSN
0022-3263

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Intramolecular anodic olefin coupling re
Intramolecular anodic olefin coupling reactions: the use of allylsilanes
โœ Kevin D. Moeller; Christine M. Hudson ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 301 KB

The use of allylsilanes as directing groups in the intramolecular electrochemical coupling of electron rich olefins has been examined. The allylsilanes were shown to provide an effective means for controlling product selectivity, and led to the formation of five-and six-membered ring products in 59-