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Intramolecular alkoxypalladation/carbonylation of alkenes

✍ Scribed by Semmelhack, Martin F.; Bodurow, Christina

Book ID
127300841
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
403 KB
Volume
106
Category
Article
ISSN
0002-7863

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Nickel-catalyzed intramolecular allylati
Nickel-catalyzed intramolecular allylation of alkenes and alkynes coupled with Ξ²-elimination or carbonylation
✍ Wolfgang Oppolzer; Manuel Bedoya-Zurita; Christopher Y. Switzer πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 319 KB

Intramolecular allylations, combined with either fl-eliminations (1 --+ 2) or carbonylations (J\_Q + 12 + 12, x'aand u+ 19 + m were catalyzed by Pt(PPh3)4, Ni(COD)/dppb, or Ni(C0)3PPh3, respectively. Pd"-catalyzed conversion of allylic acetates, alcohols and acetals A, B + F (Scheme 1) exemplifies p