Intramolecular Addition of Benzylic Radicals onto Ketenimines. Synthesis of 2-Alkylindoles.
โ Scribed by Mateo Alajarin; Angel Vidal; Maria-Mar Ortin
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 110 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
For Abstract see ChemInform Abstract in Full Text.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Radical cyclizations have attracted considerable interest in recent years, both synthetically' and mechanistically.' Although radical cyclizations of alkyl radicals onto C=C and GO bonds' have been studied extensively, radical cyclizations to C=N bonds received relatively much less attention. Radica
Bauhinoxepin J has been synthesized in four steps using an intramolecular persulfate-mediated radical addition to a quinone as the key step.