Intramolecular 1,3-diyl trapping reactions. Use of a diylophile directly linked to the diyl. Preparation of bicyclic furans.

Intramolecular diyl trapping reactions.

Intramolecular diyl trapping reactions. Arrhenius activation parameters for extrusion of nitrogen; Rate acceleration when diyl and diylophile are linked directly to one another

✍ R.Daniel Little; Charles F. Billera 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 227 KB

Arrhenius activation parameters, measured for a series of bicyclic diazenes (lb and s-2) of utility in 1,3-diyl trapping reactions, as well as the nature of the intermediate formed from deaxetation of &, have been determined.

Intramolecular 1,3-diyl trapping reactions. Use of a diylophile directly linked to the diyl. Preparation of bicyclic furans.

✦ Synopsis