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Intramolecular 1,3-dipolar cycloadditions of nitrile imines bearing an alkenyl substituent

✍ Scribed by Garanti, Luisa; Sala, Alberto; Zecchi, Gaetano

Book ID: 126935012
Publisher: American Chemical Society
Year: 1977
Tongue: English
Weight: 507 KB
Volume: 42
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00428a027

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## Abstract The readily available alkyl dicyanoacetates 1 reacted with the 1,3‐dipolar reagents arenecarbonitrile oxides 2′ and arenecarbonitrile imines 5′ to afford 1,2,4‐oxadiazol and 1,2,4‐triazol derivatives. The arenecarbonitrile oxides 2′ with electron‐donating groups on the arene ring gave p