Intramolecular 1,3-dipolar cycloaddition of alkyl azide enones and rearrangements of the triazoline intermediates. Formal total synthesis of (.+-.)-desamylperhydrohistrionicotoxin
β Scribed by Sha, Chin Kang; Ouyang, Sheng Lian; Hsieh, Der Yung; Chang, Ruei Chih; Chang, Shang Chia
- Book ID
- 121313215
- Publisher
- American Chemical Society
- Year
- 1986
- Tongue
- English
- Weight
- 676 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The thermal intramolecular azide-enone 1,3-dipolar cycloaddition to azaspirocyclic keto aziridines 17 and 18 is reported, ct-Hydroxylation and oxidation to the corresponding diketo aziridine 2 provided an intermediate in a synthetic approach toward cephalotaxine 1.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v