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Intrachain Reaction of a Pair of Reactive Groups Attached to Polymer Ends. II. Monte Carlo Study on the Intrachain Reaction Proceeding on trans/cis-Polysarcosine Chain

✍ Scribed by Sisido, Masahiko; Imanishi, Yukio; Higashimura, Toshinobu

Book ID: 126310215
Publisher: American Chemical Society
Year: 1976
Tongue: English
Weight: 568 KB
Volume: 9
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma60050a028

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Intrachain Reactions of a Pair of Reacti

Intrachain Reactions of a Pair of Reactive Groups Attached to Polymer Ends. 3. Intrachain Charge-Transfer Complex on Polysarcosine Chains Having Terminal Electron Donor and Terminal Electron Acceptor Groups in Chloroform Solution

✍ Sisido, Masahiko; Takagi, Hiroaki; Imanishi, Yukio; Higashimura, Toshinobu 📂 Article 📅 1977 🏛 American Chemical Society 🌐 English ⚖ 728 KB

Intrachain reactions of a pair of reacti

Intrachain reactions of a pair of reactive groups attached to polymer ends. V. Formation of disulfide linkages in the air-oxidation of sulfhydryl groups attached to ends of polysarcosine chain

✍ Masahiko Sisido; Fumihide Tamura; Yukio Imanishi; Toshinobu Higashimura 📂 Article 📅 1977 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 780 KB

## Abstract Polysarcosine having sulfhydryl groups attached to both ends was synthesized by the NCA method and its air‐oxidation was investigated in aqueous solution with cupric‐ion or ferric‐ion catalysts. Air‐oxidation was also conducted for a polysarcosine having one terminal sulfhydryl group. T