Intra- and Intermolecular H···Cl–Ni Bonding Patterns in a Series of Highly Preorganized Dinuclear Nickel(II) Complexes

Conformational Flexibility of the Square

Conformational Flexibility of the Square-Pyramidal Coordination Cap in a Series of Octahedral Nickel(II) Pentaamine Complexes – Magnetochemical Characterization of the Singly μ-Cl-Bridged Nickel(II) Dimer [(pyN4)Ni-Cl-Ni(pyN4)](PF6)3 [pyN4 = 2,6-Bis(1′,3′-diamino-2′-methylprop-2′-yl)pyridine]

✍ Christian Dietz; Frank W. Heinemann; Jörg Kuhnigk; Carl Krüger; Michael Gerdan; 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 394 KB 👁 2 views

The architecture of the tetrapodal pentaamine ligand 2,6-applicable), and X-ray structure determination. While the solid state structures show varying degrees of distortion of bis(1Ј,3Ј-diamino-2Ј-methylprop-2Ј-yl)pyridine (pyN 4 , 1) allows it to coordinate to nickel(II) as a square pyramidal the l