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Intersystem crossing to the lowest triplet state of phenazine following singlet excitation with a picosecond pulse

✍ Scribed by Yoshinori Hirata; Ikuzo Tanaka


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
218 KB
Volume
43
Category
Article
ISSN
0009-2614

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✦ Synopsis


The build-up of triplet-triplet absorption was measured for phcnaine by the plcovxond spectroscopy method. The mcnsurcd rntc constants for the budd-up of the T1 st.itc arc 7 X 10 " and 5 X 10" 5-l In igo-uctanc anti in tnctllanol rerpcctivcly. The fast T, burid-up would bc due to the strong spin-orbit coupling bctwccn St(na*) and T1 (nn*).