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Interpretation of1H NMR results of HD impurities in solid H2. II. Anisotropic resonance frequency shifts

โœ Scribed by I. Yu

Publisher
Springer US
Year
1992
Tongue
English
Weight
428 KB
Volume
86
Category
Article
ISSN
0022-2291

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โœฆ Synopsis

The anisotropic resonance frequency shift ~v= v(HD) -v(ortho-He singles) of the I H resonance spectrum observed in low ortho-concentration (X <_ 0.01) solid He single crystal samples is examined The observed sign and magnitude of the resonance frequency shift as well as its anisotropy are explained by the spin-rotation interaction and the second order effects of the intra-molecular dipole-dipole interaction of ortho-H2 singles. The calculations, without adjustable parameters, are in reasonable agreement with the experiments. This conclusion is at variance with the suggestion by Delrieu and Sullivan.

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