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Interpretation of the ν(CO) vibrational spectra of cluster compounds: tetrahedral anions [Fe2Ir2(CO)12]2−, [HFe2Ir2(CO)12]− and [FeIr3(CO)12]−

✍ Scribed by S.F.A. Kettle; E. Diana; P.L. Stanghellini; R.Della Pergola

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
506 KB
Volume
212
Category
Article
ISSN
0020-1693

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✦ Synopsis

The analysis of the v(C0) infrared and Raman spectra of the title compounds demonstrates the feasibility of using reliable force constant data from a model species in the interpretation of the vibratlonal spectra of another. This parameter transferability, slmllar to that used in the Extended Huckel method, should lead to a progress in understanding the vibrational CO spectra of more complex, low symmetry metal carbonyl cluster compounds.

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