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Interpretation of the potential response of PVC membrane ion-selective electrodes based on the mixed potential theory

โœ Scribed by Toshiyuki Osakai; Yoshitsugu Sato; Maya Imoto; Toru Sakaki


Book ID
116637545
Publisher
Elsevier
Year
2012
Tongue
English
Weight
475 KB
Volume
668
Category
Article
ISSN
1572-6657

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Mechanistic aspects of the K+ ion select
โœ R.D. Armstrong ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 355 KB

The mechanism of ion selective electrode membranes based on valinomycin+KBPh, in plasticized PVC is discussed in the light of recent impedance studies. In a typical membrane the K + is largely present as K+val -BPh, ion pairs. The transport number for K+val is -0.87 whilst that for BPh4 is -0.13. At