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Interpretation of the kinetic compensation effect in heterogeneous reactions: thermochemical approach

✍ Scribed by L’vov, Boris V.; Galwey, Andrew K.

Book ID
120896557
Publisher
Taylor and Francis Group
Year
2013
Tongue
English
Weight
510 KB
Volume
32
Category
Article
ISSN
0144-235X

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Compensation effects and compensation de
Compensation effects and compensation defects in kinetic and mechanistic interpretations of heterogeneous chemical reactions
✍ Andrew K. Galwey; Michael Mortimer 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 97 KB

## Abstract A case is presented for kinetic compensation effects (KCEs) reported for sets of heterogeneous rate processes to be classified. Because many of these KCEs do not conform to the ideal of isokinetic behavior, a quantitative method for describing the degree of compensation (κ) is introduce