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Interpretation of the EPR spectra of phosphoniumyl free radicals in solid state solutions

✍ Scribed by M.P. Ferroud-Plattet; Y. Ayant; E. Belorizky; P. Tordo


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
266 KB
Volume
80
Category
Article
ISSN
0038-1098

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EPR-investigations of radicals derived f
✍ Tomasz Białas; Aldona Szadowiak; Piotr Bałczewski 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 79 KB

## Abstract A selective homolysis of the CI bond in diethyl iodomethylphosphonate to give the diethoxyphosphorylmethyl radical (EtO)~2~P(O)CH~2~· was observed in EPR spectra upon γ‐irradiation and UV–vis photolysis. Analysis of stability of this radical was also investigated to show disappearance