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Interpretation of the chromatographic behavior of perhydrogenated and perfluorinated polyoxyethylene surfactants by molecular modeling

✍ Scribed by B. Herbreteau; C. Graff; F. Voisin; M. Lafosse; L. Morin-Allory

Book ID
105593752
Publisher
Springer
Year
1999
Tongue
English
Weight
639 KB
Volume
50
Category
Article
ISSN
0009-5893

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πŸ“œ SIMILAR VOLUMES

Effect of conformational changes on the
Effect of conformational changes on the reversed-phase chromatographic retention of polyoxyethylenes: quantitative interpretation based on a retention model in combination with molecular mechanics
✍ Tetsuo Okada πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 782 KB

The reversed-phase chromatographic retention of compounds having polyoayethylene (POE) as a part of the structure is known to be affected by conformational changes of the POE chains. A modified two-state model, where zig-zag and helii conformers are assumed to be more stable than others, was develop