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Interpretation of the CH stretching region of the vibrational spectra of cyclohexane

✍ Scribed by E. Mátrai; M. Gál; G. Keresztury

Book ID
103907846
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
219 KB
Volume
46
Category
Article
ISSN
1386-1425

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✦ Synopsis

The reassignment of the CH stretching vibration fundamentals of cyclohexane is made by combination of experimental--i.r, and Raman spectroscopy--and theoretical--ab initio calculation methods. The Raman active bands are determined experimentally by polarized measurements. The position and intensity of the i.r. active bands are obtained by deconvolution of the band envelopes of the vapour phase spectrum. The calculated frequencies and relative intensities are in very good agreement with the experimental values, thus confirming the feasibility of the reassignment.

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