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Interpretation of the cars spectrum of the ν1 band of 12CH4

✍ Scribed by Jens-Erik Lolck

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
388 KB
Volume
106
Category
Article
ISSN
0009-2614

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✦ Synopsis

In a recent study of the CARS spectrum of the vt band of "Clip. the expcrimenttll spectrum ~'3s found to dcxisre somewhat from theoretical predictions based on previous analyses. The present comment reports 3 prediction \vhicll lc& to a calculated CARS contour in good qrecment with the eapcrimental enc.

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Analysis of ν2, ν4 Infrared Hot Bands of
Analysis of ν2, ν4 Infrared Hot Bands of 32S16O3: Resolution of the Puzzle of the ν1 CARS Spectrum
✍ Jeffrey Barber; Engelene t.H. Chrysostom; Tony Masiello; Joseph W. Nibler; Arthu 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 309 KB

Further analysis of the high-resolution (0.0015 cm -1 ) infrared spectrum of 32 S 16 O 3 has led to the assignment of more than 3100 hot band transitions from the ν 2 and ν 4 levels to the states 2ν 2 (l = 0), ν 2 + ν 4 (l = ±1), and 2ν 4 (l = 0, ±2). These levels are strongly coupled via Fermi reso