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Interpretation of the asymmetrical ESR hyperfine spectrum of sodium pyrazine [Na P] in DME in the low temperature region. Evidence for the triple ion [Na P Na]+

✍ Scribed by C. Gooijer; W. Oosterbeek; N. H. Velthorst; C. MacLean


Publisher
John Wiley and Sons
Year
1974
Tongue
English
Weight
417 KB
Volume
6
Category
Article
ISSN
0749-1581

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✦ Synopsis


Abstract

The ESR spectrum of Na pyrazine in DME, at temperatures below −50°C, has been studied in detail. It is shown that two paramagnetic species with slightly different g values are present in the solution, i.e. the sodium pyrazine ion pair [Na P] and the iriple ion [Na P Na]^+^. The interpretation is based on the concentration dependence of the spectrum.