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Interpretation of the 17O magnetic inequivalency in 14N17O2. A theoretical and MRSD-CI study

✍ Scribed by Saba M. Mattar; Christopher Kennedy; Christine Bourque


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
543 KB
Volume
227
Category
Article
ISSN
0009-2614

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The effect of a cis-N-methyl group on the carbonyl 1 7 0 chemical shift, cis-MSCS, was investigated both from theoretical and experimental points of view in ten amide derivatives. Experimentally, it was observed that the cis-MSCS in N-methylformamide (2) corresponds to a shielding effect of 12.0 ppm