✦ LIBER ✦
Interpretation of polar aromatic solvent-induced shifts by means of the multipole approximation model
✍ Scribed by Kunio Nikki; Naoya Nakagawa
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 400 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
The aromatic solvent-induced shifts (ASIS) of various polar solutes induced by polar and non-polar aromatic solvents were determined. The protons that produce a large ASIS in non-polar solvents show a remarkable depression of the ASIS in highly polar aromatic solvents. The observed ASIS in polar aromatic solvents are in good agreement with the calculated ASIS based on the electrostatic interaction between solute and solvent molecules.