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Interpretation of Anomeric Effect in the N−C−N Unit with the Quantum Theory of Atoms in Molecules

✍ Scribed by Eskandari, Keiamars; Vila, Antonio; Mosquera, Ricardo A.

Book ID
120044290
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
466 KB
Volume
111
Category
Article
ISSN
1089-5639

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📜 SIMILAR VOLUMES

Atoms in molecules interpretation of the
Atoms in molecules interpretation of the anomeric effect in the OCO unit
✍ Antonio Vila; Ricardo A. Mosquera 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB 👁 1 views

## Abstract The conformational preferences of two model compounds for the OCH~2~O anomeric unit: methanediol and dimethoxymethane analyzed within the framework of the QTAIM theory provide a new interpretation of the anomeric effect. The characteristic stabilization of the gauche conformers of the