## Abstract The title dienophiles attack nopadiene from the less hindered side.
Interplay of dual reactivity in the reaction of pentafulvenes with 1,2,4-triazoline-3,5-diones: experimental and theoretical investigations
β Scribed by Anas, S. ;Krishnan, K. Syam ;Sajisha, V. Sanjayan ;Anju, K. Sasidharan ;Radhakrishnan, K. V. ;Suresh, Eringathodi ;Suresh, Cherumuttathu H.
- Book ID
- 120446314
- Publisher
- Royal Society of Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 916 KB
- Volume
- 31
- Category
- Article
- ISSN
- 1144-0546
- DOI
- 10.1039/b614533g
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Several 1,3-dienic terpenes of various structural types are attacked by the title dienophile from the less hindered side. The regiospecificity of attack by methyl triazolinedione(MTAD), 1, upon 1,3-conjugated dienes belonging to the [2.2.2Jbicyclooctane or the norbornane families has been shown to o
In a continuing study of cycloaddition reactions involving cyclopropane ring-containing systems (1) we have investigated the reactions of vinylcyclopropane and some substituted vinylcyclopropanes with 4-phenyl-1,2,4-triazoline-3,5-dione (PTAD) and chlorosulfonylisocyanate (CSI).