Interplay of Chiral Side Chains and Helical Main Chains in Polyisocyanates
✍ Scribed by Müller, Manfred; Zentel, Rudolf
- Book ID
- 125960927
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 474 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
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## Abstract The helical mechanoclinic deformation of a main‐chain chiral smectic elastomer, which is prepared by a crosslinking reaction under twist deformation, is investigated. The twist deformation induces a layer tilt angle that depends on the handedness of twist. The layer tilt angle in the ri
## Abstract A novel helical poly(macromonomer) [poly(M‐PS): absolute $\overline M \_{\rm w} $ = 82 800–252 000, determined by GPC/RALLS] with a polyacetylene main chain and polystyrene (PS) side chains was synthesized by the polymerization of acetylene‐terminated M‐PS [$\overline M \_{\rm n} $ = 2