First-order phase transitions in ÿnite systems can be deÿned through the bimodality of the distribution of the order parameter. This deÿnition is equivalent to the one based on the inverted curvature of the thermodynamic potential. Moreover we show that it is in a one-to-one correspondence with the
✦ LIBER ✦
Interphase Hamiltonian and first-order phase transitions: A generalization of the Lee-Yang theorem
✍ Scribed by A. G. Basuev
- Book ID
- 106541771
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2007
- Tongue
- English
- Weight
- 751 KB
- Volume
- 153
- Category
- Article
- ISSN
- 0040-5779
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## Abstract First‐order phase transitions are modelled by a non‐homogeneous, time‐dependent scalar‐valued order parameter or phase field. The time dependence of the order parameter is viewed as arising from a balance law of the structure order. The gross motion is disregarded and hence the body is
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