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Interpenetrating polymer networks of photocrosslinkable cellulose derivatives

✍ Scribed by Manjunath Kamath; John Kincaid; Braja K. Mandal


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
980 KB
Volume
59
Category
Article
ISSN
0021-8995

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✦ Synopsis


A series of interpenetrating polymer networks has been prepared from two cellulose derivatives, one of which contains cinnamate groups and the other containing randomly substituted cinnamate and ally1 groups. The latter derivative forms a crosslinked network in less than 5 min on exposure to ultraviolet radiation and can be used to make amorphous interpenetrating polymer networks containing 50% by weight loading level of crosslinked vinyl polymers. The syntheses of both derivatives and the thermal properties and film morphologies of their interpenetrating polymer networks are discussed. 0 1996 John Wi1e.y & Sons. Inc.


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## Abstract The topological entanglements between subchains of two interpenetrating polymer networks are described in the simplest approximation supposing that the primitive path of each subchain is influenced due to the shift of one network relatively to the other. The entanglement contribution to