Two photocrosslinkable NLO polymers of poly(glycidyl methacrylate) substituted with 4-nitro-4Π-hydroxyl stilbene (PGMAS) and acryloyl-functionalized epoxybased polymer (PENAA) carrying 4-nitroaniline moieties were synthesized and characterized. By using the sulfonium salt cationic photoinitiator BDS
Interpenetrating polymer networks of photocrosslinkable cellulose derivatives
β Scribed by Manjunath Kamath; John Kincaid; Braja K. Mandal
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 980 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
β¦ Synopsis
A series of interpenetrating polymer networks has been prepared from two cellulose derivatives, one of which contains cinnamate groups and the other containing randomly substituted cinnamate and ally1 groups. The latter derivative forms a crosslinked network in less than 5 min on exposure to ultraviolet radiation and can be used to make amorphous interpenetrating polymer networks containing 50% by weight loading level of crosslinked vinyl polymers. The syntheses of both derivatives and the thermal properties and film morphologies of their interpenetrating polymer networks are discussed. 0 1996 John Wi1e.y & Sons. Inc.
π SIMILAR VOLUMES
Mixtures of polystyrene derivatives (PSCS) and poly(vinyl methyl ether) (PVME) were made photocrosslinkable by chemically labeling PSCS chains with photoreactive anthracene. Miscibility of these anthracene-labeled PSCS/PVME blends was examined by light scattering under several crosslinking condition
A possible model for the formation of interpenetrating polymer networks is suggested. Phase separation is assumed to be faster than gelation. This implies that domains rich in either component grow first until late stages of spinodal decomposition. In these domains, short linear chains are crosslink
## Abstract The topological entanglements between subchains of two interpenetrating polymer networks are described in the simplest approximation supposing that the primitive path of each subchain is influenced due to the shift of one network relatively to the other. The entanglement contribution to