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Internal rotations in aliphatic molecules: n-butane and 2,2,3,3-tetrafluorobutane

โœ Scribed by Scheiner, Steve


Book ID
126154204
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
785 KB
Volume
102
Category
Article
ISSN
0002-7863

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Very low-pressure pyrolysis (VLPP) of al
โœ D. M. Golden; Z. B. Alfassi; P. C. Beadle ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 537 KB

The four species in the title were decomposed under VLPP conditions at temperatures in the vicinity of 1100ยฐK. Three model transition states were constructed that fit the low-pressure data thus obtained and that also yield If EZSS = AEZSS; 2) &OO = A&oo; 3 ) log Alloo = 16.4 per C-C bond broken. Th