Internal rotation of 1,4-dichlorobutyne-2
โ Scribed by S. Suzuki
- Book ID
- 103204126
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 358 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0022-2860
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
trimethylsilylethenol The ~intramolecular rotation of the two mesityl rings in 2,2-dimesityl-Iwhich leads to propeller enantiomerization is correlated. value for the enantiomerization is 11.1 kcal mol-1, a value intermediate The AGc the l-isopropyl and l-tert-butyl analogs. between those for 2,2-Dim
Addition of (pseudo) halogens across the triple bond of 1,4-dichlorobut-2-yne, followed by a 1,4-elimination, provides a very simple preparation of ten novel butadienes. In recent years there has been a great deal of interest in asymmetrically substituted butadienes, both for theoretical reasons an