✦ LIBER ✦

Internal rotation in CH3CD3: Raman spectroscopy of torsional overtones

✍ Scribed by K. Van Helvoort; R. Fantoni; W.Leo Meerts; J. Reuss

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 650 KB
Volume: 128
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80660-1

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✦ Synopsis

CHJCDa torsional overtones have been observed by spontaneous Raman scattering in a laser intracavity apparatus. Au = 2 multiplet transitions up to the sixth torsional level have been measured. The new data were combined with Au = 0 transi@ons from microwave and molecule-beam avoided crossing experiments and with Au = 1 IR measurements. The barrier parameters V3 = 997.72 f 0.32 cm-' and V6 = 8.45 f 0.37 cm-' have been determined.

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