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Internal oxidation of ternary alloys. Part II: Kinetics in the presence of an external scale

✍ Scribed by S. W. Guan; H. C. Yi; W. W. Smeltzer

Publisher: Springer-Verlag
Year: 1994
Tongue: English
Weight: 706 KB
Volume: 41
Category: Article
ISSN: 0030-770X
DOI: 10.1007/bf01113373

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📜 SIMILAR VOLUMES

Internal oxidation of ternary alloys. Pa

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Transition from internal to external oxi

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The Internal Oxidation of Ternary Alloys. IV: The Internal Oxidation of the Most-Reactive Component Beneath External Scales of the Component Having Intermediate Reactivity

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Oxidation of olefins by palladium(II). Part XIV. Product distribution and kinetics of the oxidation of ethene by PdCl3 (pyridine)− in aqueous solution in the presence and absence of CuCl2: a modified Wacker catalyst with altered reactivity

✍ John W. Francis; Patrick M. Henry 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 899 KB

In the absence of CuC12, ethene was oxidized to ethanal by PdCl,(pyridine) -in aqueous solution by the rate expression: \* where K' is the equilibrium constant for n-complex formation between ethene and PdCl,(Py) -(Py =pyridine). This rate expression is of the same form as that previously found for