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Internal Electron Transfer in Cytochrome c Oxidase Is Coupled to the Protonation of a Group Close to the Bimetallic Site

✍ Scribed by Hallen, Stefan; Brzezinski, Peter; Malmstroem, Bo G.


Book ID
111913551
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
654 KB
Volume
33
Category
Article
ISSN
0006-2960

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Electronic structures of heme a of cytoc
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## Abstract The electronic structures of heme __a__ of cytochrome __c__ oxidase in the redox states were studied, using hybrid density functional theory with a polarizable continuum model and a point charge model. We found that the most stable electronic configurations of the d electrons of the Fe