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Intermolecular Repulsions in Adsorbed Layers

✍ Scribed by G.L. Aranovich; C. Sangwichien; M.D. Donohue


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
148 KB
Volume
227
Category
Article
ISSN
0021-9797

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✦ Synopsis


Adsorbate-adsorbate interactions are analyzed in the framework of the Ono-Kondo model. The results show that, at large amounts of adsorption, intermolecular interactions in the adsorbed phase are repulsive. In the range of small adsorption, microporous systems also can show repulsions due to limitations of the adsorption space. This effect also is possible in macroporous adsorbents with active site spacing that is less than that of the adsorbate bulk liquid.


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