Intermolecular radical reactions of unsaturated chromium and tungsten carbene complexes
β Scribed by Merlic, Craig A.; Xu, Daqiang
- Book ID
- 111942391
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 323 KB
- Volume
- 113
- Category
- Article
- ISSN
- 0002-7863
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Treatment of (CO) 5 W=C(NMe 2 )CH=CH-Ar-(OH)(H)CΟ΅CH (1a-b) [a: -Ar-=1,4-C 6 H 4 -; b: -Ar-= 2,5-C 4 H 2 S-] with W(CO) 5 (THF) in methanol yields the nonsymmetrical bis(alkenylcarbene)-bridged ditungsten complexes (CO) 5 W= C(NMe 2 )CH=CH-Ar-CH=CH(OMe)C=W(CO) 5 (3a-b). Similarly, the symmetrical bis