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Intermolecular magnetic exchange interactions in structural polytypes of iodobis(morpholyldithiocarbamate)iron (III)

✍ Scribed by J.M. Grow; G.L. Robbins; H.H. Wickman

Book ID: 103016530
Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 360 KB
Volume: 43
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80760-9

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✦ Synopsis

Reccivcd 16 June 1976 lllc title complex exhibits a number of ullotropcs or solvent adducts, scvcnl of which show cooperative ma_gnctic tnnsitions in the helium tcmpcraturc range. Thcsc materials rcprcsent a uschul class of metal complcxcs in which intermolccutar magnetic cxchangc bctwccn identical molcculcs in variable Iatticc orientations may bc studied. Low tcmperaturc hfossbaucr hfs propertics of four spccics arc rcportcd hcrc; this information is used to dctcrminc the cryst;ll ticld splitting within the ground quartet state of the complex.

Intermediate-spin haIobis(dithiocarbamato)iron(III)

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