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Intermolecular Interactions in Polymorphs of Trinuclear Gold(I) Complexes: Insight into the Solvoluminescence of Au I3 (MeNCOMe) 3

✍ Scribed by White-Morris, Rochelle L.; Olmstead, Marilyn M.; Attar, Saeed; Balch, Alan L.


Book ID
127131958
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
211 KB
Volume
44
Category
Article
ISSN
0020-1669

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## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5‐disubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their