Intermolecular Interactions in Polymorphs of Trinuclear Gold(I) Complexes: Insight into the Solvoluminescence of Au I3 (MeNCOMe) 3
β Scribed by White-Morris, Rochelle L.; Olmstead, Marilyn M.; Attar, Saeed; Balch, Alan L.
- Book ID
- 127131958
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 211 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
p = 33.30 cm I . 2$,,, = 45.0". 9702 reflections collected, 5062 independent (R,,, = 0.0642) and 4629 observed [F,>4a(Fo)]. The structure was solved by direct methods and refined on F2 using SHELXTL software. Data were corrected for Lorentz and polarization effects. No absorption correction was appl
## Abstract Compounds [{Au(pz)(PPh~3~)}~2~] (pz=3,5βdisubstituted pyrazolato; R=BuOC~6~H~4~ (bp), 1; R=C~8~H~17~OC~6~H~4~ (op), 2; R=C~6~H~13~OC~6~H~4~ (hp), 3) were easily obtained by reaction of [Au(NO~3~)(PPh~3~)] and the corresponding pyrazolato ligand. They exhibit similar NMR patterns, their