Intermolecular insertion of the carbene ligand of pentacarbonyl tungsten benzylidenes into the M–H bond of transition metal hydrido complexes
✍ Scribed by Helmut Fischer; Holger Jungklaus
- Book ID
- 108354661
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- English
- Weight
- 184 KB
- Volume
- 572
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Treatment of the complexes [Re(NO)~2~(PR~3~)~2~][BAr^F^~4~] (R = Cy, 1 a; R = __i__Pr, 1 b) with phenyldiazomethane gave the cationic benzylidene species [Re{CH(C~6~H~5~)}(NO)~2~(PR~3~)~2~][BAr^F^~4~] (2 a and 2 b) in good yields. Upon reaction of 2 a and 2 b with acetonitrile, the cons
The reaction of 4-X-5-alkylthio-3H-1,2-dithiole-3-thione (1) with Fischer carbene complexes (2) gives, as a main product, cyclohexa dithiine derivatives due to insertion of the carbene ligand into the C3 C4 bond of the heterocycle. The reaction takes place with 1 where the alkyl substituents in posi