𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Intermolecular insertion of the carbene ligand of pentacarbonyl tungsten benzylidenes into the M–H bond of transition metal hydrido complexes

✍ Scribed by Helmut Fischer; Holger Jungklaus


Book ID
108354661
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
184 KB
Volume
572
Category
Article
ISSN
0022-328X

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Metal Nitrosyl Reactivity: Acetonitrile-
✍ C. M. Frech; O. Blacque; H. W. Schmalle; H. Berke 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 932 KB

## Abstract Treatment of the complexes [Re(NO)~2~(PR~3~)~2~][BAr^F^~4~] (R = Cy, 1 a; R = __i__Pr, 1 b) with phenyldiazomethane gave the cationic benzylidene species [Re{CH(C~6~H~5~)}(NO)~2~(PR~3~)~2~][BAr^F^~4~] (2 a and 2 b) in good yields. Upon reaction of 2 a and 2 b with acetonitrile, the cons

Insertion of Fischer carbene complexes i
✍ Alejandro M. Granados; Jerónimo Kreiker; Rita H. de Rossi 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 154 KB

The reaction of 4-X-5-alkylthio-3H-1,2-dithiole-3-thione (1) with Fischer carbene complexes (2) gives, as a main product, cyclohexa dithiine derivatives due to insertion of the carbene ligand into the C3 C4 bond of the heterocycle. The reaction takes place with 1 where the alkyl substituents in posi