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Intermolecular hydrophosphination of alkynes and related carboncarbon multiple bonds catalyzed by ytterbium–imine complexes

✍ Scribed by Ken Takaki; Mitsuhiro Takeda; Go Koshoji; Tetsuya Shishido; Katsuomi Takehira

Book ID: 104231337
Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 99 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01280-1

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## Abstract Chromium alkoxy alkynyl Fischer carbene complexes react with symmetrical internal alkynes to form new and different organometallic species, which result from consecutive insertions of several alkyne units and carbonyl groups into the metal–carbon bond. The insertion sequence can be cont