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Intermolecular Hydrogen-Bonding Pattern of a Glycosyl Donor: The Key to Understanding the Outcome of Sialylation

✍ Scribed by Leonid O. Kononov; Nelly N. Malysheva; Elena G. Kononova; Anna V. Orlova

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
395 KB
Volume
2008
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

Changes in the hydrogen‐bonding pattern in solutions of glycosyl donor induced by the addition of external amides/imides or by concentration changes influence the yield and stereoselectivity of sialylation. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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## Abstract A procedure is given to derive an explicit charge‐transfer contribution from the Murrell–Randic–Williams formula, and to implement it in the framework of an additive procedure for the computation of intermolecular interaction energies, as a sum of electrostatic, repulsion, polarization,