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Intermolecular Hydroamination of 1,3-Dienes Catalyzed by Bis(phosphine)carbodicarbene–Rhodium Complexes

✍ Scribed by Goldfogel, Matthew J.; Roberts, Courtney C.; Meek, Simon J.

Book ID
124086881
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
840 KB
Volume
136
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES

Asymmetric double hydroboration of 1,3-d
Asymmetric double hydroboration of 1,3-dienes catalyzed by chiral phosphine-rhodium complexes
✍ Yonetatsu Matsumoto; Tamio Hayashi 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 310 KB

Suntnuzry: Reaction of I-phenyl-1,3-butadiene with catecholborane in the presence of a rhodium catalyst bearing ~a~lphosphine ligand such as PPh3 or dppf proceeded regioselectively to give, after oxidation, anti-l-phenyl-1,3-butanediol in a good yield. Use of (R)-BINAP as a chiral ligand for the cat