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Intermolecular FeCl3-Catalyzed Hydroamination of Styrenes

✍ Scribed by Julien Michaux; Vincent Terrasson; Sylvain Marque; Johny Wehbe; Damien Prim; Jean-Marc Campagne

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
84 KB
Volume
2007
Category
Article
ISSN
1434-193X

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✦ Synopsis

Abstract

Hydroamination reactions of vinylarenes with nonnucleophilic nitrogen derivatives (p‐toluenesulfonamide, p‐nitroaniline, p‐nitrobenzamide, ...) catalyzed by FeCl~3~ are described. Interestingly, these reactions are catalyzed by an environmentally friendly and an inexpensive catalyst in the absence of any ligand or cocatalyst. (Β© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

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