## Detection of 4-iodo-2,2-dimethyloctanenitrile and 2-iodo-2-methylpropanenitrile proved an operation of two types (I and II) of initiation in the I-ATRA reaction. 4-Iodo-2,2-dimethyloctanenitrile, resulting from the isobutyronitrile radical attack onto 1-hexene followed by the iodine atom transfer
Intermolecular energy transfer in two-channel unimolecular reactions: the pyrolysis of 1-iodopropane
β Scribed by Brendan J. Gaynor; Robert G. Gilbert; Keith D. King
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 488 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
The geometry corresponding to the minimum potential energy of an O-, H,O cluster is calculated at the second order Moller-Plesset approximation level as a function of the O-O-distanze (path 1) and H-O-distance (path 2). Along path 1 the oxygen atoms are inequivalent for O-O distances larger than 2 A
An improved ion beam apparatus is used to study the nascent state distribution of products m the Ar+ + N, charge transfer reaction at 0.28 eV collision energy. The rotational distribution of the minor v = 0 vibrational channel under single-collision conditions can be characterized by ,a Boltzmann di
The reaction Ar+(2Pgn) + N,(X tzk,, u = 0) -Ar + Nt(X zag, u") was studred at 1.1 eV coU~~~on energy usmg a crossed-beam method. in contrast wrth results at higher and lower cok~on energtes. the scattenng diagram obtruned at thts energy exhtbtts clearly resolved structure whtch suggests that product