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Intermediates in the photolyses of mesoionic thiadiazoles: detection of heterocumulenes by infrared

✍ Scribed by R.M. Moriarty; R. Mukherjee; O.L. Chapman; David R. Eckroth

Book ID: 104247379
Publisher: Elsevier Science
Year: 1971
Tongue: French
Weight: 170 KB
Volume: 12
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)96450-0

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✦ Synopsis

We reported previously that photolyses of mesoionic thiadlazoles in solution yielded thioamides and elemental sulfur possibly via initial pho--'To.5

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## Abstract The mesoionic derivative 4‐phenyl‐5‐[4‐nitrocinnamoyl]‐1,3,4‐thiadiazolyl‐2‐phenylamine chloride (MI‐D) has antitumoral and anti‐inflammatory effects. In this study, we present aspects of its metabolism and toxicity in mice. MI‐D was metabolized __in vitro__ by liver microsome, generati