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Intermediates in the electrolytic reduction of 2-pyridyl-1,3-indandiones in aprotic media

✍ Scribed by Yu. A. Benders; Ya. P. Stradyn'; L. M. Baider; L. Kh. Baumane; R. A. Gavar

Book ID
112349048
Publisher
Springer US
Year
1983
Tongue
English
Weight
617 KB
Volume
19
Category
Article
ISSN
0009-3122

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Electrochemical reduction of quarternize
Electrochemical reduction of quarternized 2-pyridinio-1,3-indandiones at a mercury electrodeβ€”I. Electroreduction in aprotic medium
✍ J. Stradins; J. Benders; V. Kadysh πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 717 KB

The electrochemical reduction of 2-pyridinio-1,3-indandiones (quarternized pyrophthalones and quinophthalones as well as N-ylides) was studied at a dropping mercury electrode in aprotic medium (DMF). The first one-electron stage ranging from -1.1 to -1.9 V leads to free-radical species in which the

Electrochemical reduction of quarternize
Electrochemical reduction of quarternized 2-pyridinio-1,3-indandiones on mercury electrodeβ€”II. Electroreduction in protogenic medium
✍ J. Benders; V. Kadysh; E. Lavrinovičs; J. Stradins πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 892 KB

The electroreduction mechanism of 2-pyridinio-and 2-quinolynio-1,34ndandiones (pyrophthalones, quinophthalones, N-ylides of 1,3-indandione) was established using methods of classical polarography, cyclic voltammetry and controlled-potential electrolysis (CPE) on mercury electrode in protogenic mediu