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Intermediates in nucleophilic aromatic substitution. VII. Stopped-flow temperature-jump study of the transient 1,3-methoxide ion adduct of 2,4,6-trinitroanisole in methanol

โœ Scribed by Bernasconi, Claude F.


Book ID
121417353
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
292 KB
Volume
93
Category
Article
ISSN
0002-7863

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Aromatic nucleophilic substitution VIII.
โœ S. Sekiguchi; T. Takei; T. Aizawa; K. Okada ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Ever since Servis' first observed by NMR spectrometry that in DMSO much faster formation of 1,3\_disubstituted anionic o complex (hereinafter referred to as 1,3-adduct) from 2,4,6\_trinitroanisole (TNA) and 'OCH3 is followed by a much slower attack on the l-position, considerable attention has been