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Intermediates in cyclopropylcarbinyl-cyclobutyl-homoallyl-rearrangement

✍ Scribed by M. Geisel; C.A. Grob; W. Santi; W. Tschudi

Book ID
104245384
Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
196 KB
Volume
13
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES

The Cyclopropylcarbinyl-Cyclobutyl-Homoa
The Cyclopropylcarbinyl-Cyclobutyl-Homoallylic Rearrangement. Part III. Evidence for a symmetrical intermediate and for two discrete rearrangement processes
✍ Manfred Geisel; Cyril A. Grob; RenΓ© P. Traber; Werner Tschudi πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 German βš– 879 KB

## Abstract In buffered 70% aqueous dioxane the cyclopropylcarbinyl (**1**‐X), __endo__‐cyclobutyl (**2**‐X) and homoallylic (**3**‐X) derivatives (X = nucleofuge) react to give the same mixture of alcohols **1**‐OH and **3**‐OH by way of a common intermediate, the symmetrical homoallylic ion **22*