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Intermediate steps in autoxidations: I. Enolization and deuteration of acetophenones in acetic acid

✍ Scribed by H.J. den Hertog Jr.; E.C. Kooyman

Book ID
113173004
Publisher
Elsevier Science
Year
1966
Tongue
English
Weight
743 KB
Volume
6
Category
Article
ISSN
0021-9517

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## Abstract A detailed picture is given of the mechanisms involved in the oxidation of acetophenones with oxygen to benzoic acids, at 150Β°, using manganese salts as catalysts and butyric acid as solvent. Kinetic studies indicate that the reaction is first‐order with respect to ketone and butyric a